Reaction of polyhalopyridines 4. Reaction of mercaptopolychloropyridines with fluorine-containing xenon compounds

Abstract

A method has been developed for the perfluoroalkylation of mercaptopolychloropyridines by the thermolysis of xenon(II) perfluoroalkanecarboxylates, obtained by the reaction of xenon difluoride and perfluoroalkanecarboxylic acids, in the presence of the appropriate thiol. Perfluoroalkylthio derivatives of polychloropyridines have been synthesized. The fluorosulfonyl derivatives of tetrachloropyridine and of tetrachloropyridine N-oxide were obtained by the action of XeF₂ on mercaptotetrachloropyridine dissolved in aqueous HF.

How to Cite
Sipyagin, A. M.; Pomytkin, I.;A.; Pal'tsun, S. V.; Aleinikov, N. N. Chem. Heterocycl. Compd. 1994, 30, 52. [Khim. Geterotsikl. Soedin. 1994, 58.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01164732