Reactions of polyhalopyridines. 5. Reaction of 2,3,5,6-tetrachloro-4-trifluoromethylthiopyridine with nucleophilic reagents
Abstract
The reaction on 2,3,5,6-tetrachloro-4-trifluoromethylthiopyridine with various nucleophilic reagents has been studied. It was shown that the CF3S group is readily replaced under the action of O- and S-nucleophiles. Competition was detected between replacement of an α-chlorine atom on the pyridine ring and of the fluorinecontaining group under the action of N-nucleophilic reagents. New derivatives of trichlorotrifluoromethylthiopyridine with nitrogen-containing substituents have been synthesized.
How to Cite
Sipyagin, A. M.; Pal'tsun, S. V.; Pomytkin, I. A.; Aleinikov, N. N. Chem. Heterocycl. Compd. 1994, 30, 56. [Khim. Geterotsikl. Soedin. 1994, 63.]
For this article in the English edition, see DOI https://doi.org/10.1007/BF01164733
